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Total Synthesis of the Proposed Structure of Trocheliophorolide D
- Hwang, Soonho;
- Kim, Jae Hyun;
- Kim, Hak Sung;
- Kim, Sanghee
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24초록
The proposed structure of trocheliophorolide D was synthesized, and the NMR spectra of the synthetic compound proved to be inconsistent with those of the natural product. Our synthesis features the construction of the 2-butenolide moiety by using an aldol strategy and assembly of the triyne system during the final stage of the synthesis.
키워드
Lipids; Polyynes; Total synthesis; Cross-coupling; Aldol reactions; ANNONACEOUS ACETOGENINS; POLYACETYLENES; DERIVATIVES; CHEMISTRY; STRATEGY; MIMICRY; ROUTE
- 제목
- Total Synthesis of the Proposed Structure of Trocheliophorolide D
- 저자
- Hwang, Soonho; Kim, Jae Hyun; Kim, Hak Sung; Kim, Sanghee
- 발행일
- 2011-12
- 유형
- Article
- 권
- 2011
- 호
- 36
- 페이지
- 7414 ~ 7418
- 언어
- ENG
- 출판사
- WILEY-V C H VERLAG GMBH
- 발행국가
- 독일
- 분량
- 5 페이지
- ISSN
- E 1099-0690
P 1434-193X