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Oxygen-Independent Decarbonylation of Aldehydes by Cyanobacterial Aldehyde Decarbonylase: A New Reaction of Diiron Enzymes
- Das, Debasis;
- Eser, Bekir E.;
- Han, Jaehong;
- Sciore, Aaron;
- Marsh, E. Neil G.
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Just add water: Structurally, cyanobacterial aldehyde decarbonylases are members of the non-heme diiron oxygenase family of enzymes. However, the enzyme catalyzes the hydrolysis of aliphatic aldehydes to alkanes and formate (see scheme), in an oxygen-independent reaction. This unusual and chemically difficult reaction most likely involves free radical intermediates. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
키워드
biofuels; free radicals; hydrolysis reactions; metalloproteins; radical traps; TRACHOMATIS RIBONUCLEOTIDE REDUCTASE; MANGANESE(IV)/IRON(III) COFACTOR; METHANE MONOOXYGENASE; ELECTRON-TRANSFER; FATTY ALDEHYDE; PISUM-SATIVUM; BIOSYNTHESIS; PLANT; IRON; DIOXYGEN
- 제목
- Oxygen-Independent Decarbonylation of Aldehydes by Cyanobacterial Aldehyde Decarbonylase: A New Reaction of Diiron Enzymes
- 저자
- Das, Debasis; Eser, Bekir E.; Han, Jaehong; Sciore, Aaron; Marsh, E. Neil G.
- 발행일
- 2011-07-25
- 유형
- Article
- 권
- 50
- 호
- 31
- 페이지
- 7148 ~ 7152
- 언어
- ENG
- 출판사
- WILEY-V C H VERLAG GMBH
- 발행국가
- 독일
- 분량
- 5 페이지
- ISSN
- E 1521-3773
P 1433-7851