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TOF-2: A large 1D channel thorium organic framework
- Ok, Kang Min;
- Sung, Jaeyoung;
- Hu, Gang;
- Jacobs, Robert M. J.;
- O'Hare, Dermot
Citations
WEB OF SCIENCE
129Citations
SCOPUS
130초록
A new neutral 1D channel thorium organic framework material (TOF-2) has been synthesized under hydrothermal conditions. TOF-2 exhibits a hexagonal channel structure consisting of eight-coordinate ThO6F2 polyhedra and 1,3,5-benzentricarboxylate ligands. The channels run along the c-axis and are approximately 13 angstrom in diameter. The single-crystal X-ray structure suggests that the amount of void space is 41%. The structure is stable to ca. 400 degrees C. Gas adsorption measurements show deferential gas uptake behavior.
키워드
Organic Compound; Thorium; Article; Chemical Structure; Crystal Structure; Nanotechnology; Synthesis; Thermal Analysis; X Ray Diffraction; X Ray Powder Diffraction; BOND-VALENCE PARAMETERS; CRYSTAL-STRUCTURE; DESIGN; CHEMISTRY; SOLIDS
- 제목
- TOF-2: A large 1D channel thorium organic framework
- 저자
- Ok, Kang Min; Sung, Jaeyoung; Hu, Gang; Jacobs, Robert M. J.; O'Hare, Dermot
- 발행일
- 2008-03
- 유형
- Article
- 권
- 130
- 호
- 12
- 페이지
- 3762 ~ 3763
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 2 페이지
- ISSN
- E 1520-5126
P 0002-7863