Visible-Light-Promoted Synthesis of Benzimidazoles

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초록

A simple and environmentally-friendly synthetic method for benzimidazoles, which are important structural motifs in many applications owing to their various biological functions, has been developed. The reaction of o-phenylenediamine and a variety of aliphatic/aromatic aldehydes in methanol proceeds at room temperature with only natural sources, molecular oxygen and visible light.

키워드

Synthetic methods; Photochemistry; Nitrogen heterocycles; PHOTOREDOX CATALYSIS; 2-SUBSTITUTED BENZIMIDAZOLES; GREEN CHEMISTRY; SOLAR-ENERGY; TRIFLUOROMETHYLATION; DERIVATIVES; AIR; PHOTOCATALYSIS; BENZOTHIAZOLES; ALKYLATION
제목
Visible-Light-Promoted Synthesis of Benzimidazoles
저자
Park, Sehyun; Jung, Jaehun; Cho, Eun Jin
DOI
10.1002/ejoc.201402141
발행일
2014-07
유형
Article
저널명
European Journal of Organic Chemistry
권
2014
호
19
페이지
4148 ~ 4154