Synthesis of fluoroalkylated alkynes via visible-light photocatalysis

Iqbal, Naila; Iqbal, Naeem; Han, Sung Su; Cho, Eun Jin

doi:10.1039/c8ob02486c

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Synthesis of fluoroalkylated alkynes via visible-light photocatalysis

Iqbal, Naila;
Iqbal, Naeem;
Han, Sung Su;
Cho, Eun Jin

Citations

WEB OF SCIENCE

28

Citations

SCOPUS

29

초록

Fluoroalkylated alkynes, which are versatile building blocks for the synthesis of various biologically active organofluorine compounds, were synthesized from easily available alkynyl halides and fluoroalkyl halides by visible-light photocatalysis. Addition of fluoroalkyl radicals to alkynes and subsequent dehalogenation selectively yielded fluoroalkylated alkynes.

키워드

PERFLUOROALKYL IODIDES; CARBOXYLIC-ACIDS; TERMINAL ALKYNES; TRIFLUOROMETHYLATION; FLUORINE; DIFLUOROALKYLATION

제목: Synthesis of fluoroalkylated alkynes via visible-light photocatalysis

저자: Iqbal, Naila; Iqbal, Naeem; Han, Sung Su; Cho, Eun Jin

DOI: 10.1039/c8ob02486c

발행일: 2019-02

유형: Article

저널명: Organic and Biomolecular Chemistry

권: 17

호: 7

페이지: 1758 ~ 1762