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Metal-catalyzed bond reorganization of 1,3-diynes
- Cho, Eun Jin;
- Kim, Mansuk;
- Lee, Daesung
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1초록
1,3-Diynes possessing propargylic heteroatom substituents provide functionalized 1,5-dien-3-ynes when catalyzed by platinum and gold. This rearrangement implies the involvement of metallotropic [1,3]-shift of the intermediate alkynyl metal carbene species. (c) Wiley-VCH Verlag GmbH & Co.
키워드
rearrangement; 1,3-diyne; 1,5-dien-3-yne; metal carbene; metallotropic [1,3]-shift; ALKYNYL CARBENE COMPLEXES; RING-CLOSING METATHESIS; CYCLOISOMERIZATION REACTIONS; RAUTENSTRAUCH REARRANGEMENT; HOMOGENEOUS CATALYSIS; VINYLIDENE COMPLEXES; ENYNES; GOLD; CYCLIZATION; ACETATES
- 제목
- Metal-catalyzed bond reorganization of 1,3-diynes
- 저자
- Cho, Eun Jin; Kim, Mansuk; Lee, Daesung
- 발행일
- 2006-07
- 유형
- Article
- 권
- 2006
- 호
- 14
- 페이지
- 3074 ~ 3078
- 언어
- ENG
- 출판사
- WILEY-V C H VERLAG GMBH
- 발행국가
- 독일
- 분량
- 5 페이지
- ISSN
- P 1434-193X