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Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis
- Iqbal, Naeem;
- Choi, Sungkyu;
- Kim, Eunjin;
- Cho, Eun Jin
Citations
WEB OF SCIENCE
223Citations
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227초록
A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF3I, Ru(Phen)(3)Cl-2, and DBU. This process works especially well for terminal alkenes to give alkenyl-CF3 products with only E-stereochemistry. The mild reaction conditions enable the trifluoromethylation of a range of alkenes that bear various functional groups.
키워드
BOND FORMATION; REDUCTIVE ELIMINATION; TERMINAL ALKENES; PHOTOCATALYSIS; FLUORINE; ACIDS; ORGANOCATALYSIS; CYCLOADDITIONS; CHEMISTRY; ALDEHYDES
- 제목
- Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis
- 저자
- Iqbal, Naeem; Choi, Sungkyu; Kim, Eunjin; Cho, Eun Jin
- 발행일
- 2012-12
- 유형
- Article
- 권
- 77
- 호
- 24
- 페이지
- 11383 ~ 11387
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 5 페이지
- ISSN
- E 1520-6904
P 0022-3263