Facile Synthesis of BiVO 4 for Visible-Light-Induced C−C Bond Cleavage of Alkenes to Generate Carbonyls

  • Han, Sung Su; 
  • Park, Joon Yong; 
  • Hwang, Ho Seong; 
  • Choe, Hye Rin; 
  • Nam, Ki Min; 
  • ... Cho, Eun Jin
Citations

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초록

BiVO 4 crystals synthesized by an ultrasonic-assisted method (Sono-BiVO 4 ) showed improved efficiency as a heterogeneous photocatalyst under visible-light irradiation. Sono-BiVO 4 was successfully used for the C−C bond cleavage of alkenes to generate carbonyl compounds. Styrene derivatives were converted into carbonyl compounds in the presence of Sono-BiVO 4 under highly sustainable conditions requiring only natural sources, that is, molecular oxygen, visible light, and water at room temperature. Additionally, Sono-BiVO 4 could be easily separated from the reaction mixture and reused. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

키워드

alkene; bismuth vanadate; C−C bond cleavage; molecular oxygen; photocatalysis; Bismuth compounds; Carbonyl compounds; Light; Molecular oxygen; Olefins; Photocatalysis; Styrene; Bismuth vanadates; Bond cleavages; Facile synthesis; Heterogeneous photocatalysts; Reaction mixture; Styrene derivatives; Visible light induced; Visible-light irradiation; Vanadium compounds
제목
Facile Synthesis of BiVO 4 for Visible-Light-Induced C−C Bond Cleavage of Alkenes to Generate Carbonyls
저자
Han, Sung Su; Park, Joon Yong; Hwang, Ho Seong; Choe, Hye Rin; Nam, Ki Min; Cho, Eun Jin
DOI
10.1002/cssc.201900439
발행일
2019-07
유형
Article
저널명
ChemSusChem
권
12
호
13
페이지
3018 ~ 3022