Anchor-Functionalized Push-Pull-Substituted Bis(tridentate) Ruthenium(II) Polypyridine Chromophores: Photostability and Evaluation as Photosensitizers

초록

Stable push-pull substituted heteroleptic bis(tridentate) ruthenium(II) polypyridine complexes with COOH or 2,2-bipyridine anchor groups have been prepared and characterized by 1H, 13C and 15N NMR 1D and 2D spectroscopy, infrared spectroscopy, elemental analysis, high-resolution ESI mass spectrometry, electrochemistry, UV/Vis absorption spectroscopy, luminescence spectroscopy, and density functional calculations. The complexes feature a pronounced electronic directionality and high absorption wavelengths up to max = 544 nm extending to 720 nm as a result of favorable push-pull substitutions. A remarkable photostability in the presence of water and coordinating ions (I-) was discovered for the tridentate complexes when compared with the standard ruthenium sensitizer N719 and tris(bidentate) [Ru(bpy)3](PF6)2, which are highly photolabile under the same conditions (photodissociation/photosubstitution). The complexes were studied as photosensitizers in dye-sensitized solar cells. The incident photon-to-current conversion efficiency follows the absorption spectra into the NIR region. However, the high positive charge of the complexes (2+) favors the recombination of the injected electrons with I3- of the redox electrolyte, which is evidenced by high dark currents and short electron recombination lifetimes, leading to low cell performances compared with cells with the negatively charged N719 dye.

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