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Direct Conversion of Propylene Oxide to 3-Hydroxy Butyric Acid Using a Cobalt Carbonyl Ionic Liquid Catalyst
- Rajendiran, Senkuttuvan;
- Park, Gyoosoon;
- Yoon, Sungho
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WEB OF SCIENCE
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14초록
The reported catalytic system demonstrates the possibility of efficient mass production of 3-hydroxybutyric acid (3-HBA) from inexpensive raw materials. The direct coupling of propylene oxide, water, and CO was catalyzed by 1-butyl-3-methylimidazolium cobalt tetracarbonyl ([Bmim][Co(CO)(4)]) ionic liquid to form 3-HBA with >99% conversion (49% selectivity) under mild conditions.
키워드
ionic liquid; β-hydroxy carboxylic acids; [Bmim][Co(CO)(4)]; carbonylation; water; HYDROGENATION
- 제목
- Direct Conversion of Propylene Oxide to 3-Hydroxy Butyric Acid Using a Cobalt Carbonyl Ionic Liquid Catalyst
- 저자
- Rajendiran, Senkuttuvan; Park, Gyoosoon; Yoon, Sungho
- 발행일
- 2017-08
- 유형
- Article
- 저널명
- Catalysts
- 권
- 7
- 호
- 8
- 언어
- ENG
- 출판사
- MDPI AG
- 발행국가
- 스위스
- ISSN
- P 2073-4344