Insights of pristine stainless steel mesh oxygen evolution reaction in diverse concentrations of potassium hydroxide

초록

Stainless steel, a cost-effective Fe, Ni, and Cr alloy, is a promising electrode material for green electrochemical energy conversion systems. Accordingly, this study investigated the effect of potassium hydroxide concentration (KOH; 0.1, 1.0, and 6.0 M) on the oxygen evolution reaction (OER) activity of pristine stainless-steel mesh (pre-SSM) used for the different concentrations denoted by SSM-0.1, SSM-1.0, and SSM-6.0). In particular, SSM-6.0 showed satisfactory OER activity with a low overpotential of 223 mV, and a Tafel slope of 44 mV dec-1 was required to achieve a current density of 10 mA cm−2. This remarkable performance of the electrode resulted from the 6.0 M KOH solution having a considerably higher theoretical specific conductivity (0.6266 S cm−1) than the 1.0 M (0.2153 S cm−1) and 0.1 M (0.0241 S cm−1) KOH solutions. © 2022 Elsevier B.V.

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