Visible-Light-Promoted Synthesis of Dibenzofuran Derivatives

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초록

Dibenzofurans are naturally occurring molecules that have received considerable attention for a variety of practical applications, such as in pharmaceuticals and electronic materials. Herein, an efficient and eco-friendly method for the synthesis of dibenzofuran derivatives via intramolecular C-O bond formation, which involves the in situ production of a diazonium salt, is described. The transformation requires a diazotizing agent and is promoted by the use of an organic photosensitizer under visible-light irradiation.

키워드

COUPLING REACTIONS; ORGANIC-SYNTHESIS; DIRECT ARYLATION; DIAZONIUM SALTS; CARBAZOLES; CYCLIZATION; CATALYSIS; 2-AMINO-2'-HYDROXY-1,1'-BIARYLS; PHYTOALEXINS; COMPLEXES
제목
Visible-Light-Promoted Synthesis of Dibenzofuran Derivatives
저자
Cho, Ji Young; Roh, Geum-bee; Cho, Eun Jin
DOI
10.1021/acs.joc.7b02796
발행일
2018-01
유형
Article
저널명
The Journal of Organic Chemistry
권
83
호
2
페이지
805 ~ 811