Fluorogenic Hg2+-selective chemodosimeter derived from 8-hydroxyquinoline

  • Song, Ki Cheol; 
  • Kim, Jun Soo; 
  • Park, Sang Mi; 
  • Chung, Kee-Choo; 
  • Ahn, Sangdoo; 
  • 외 1명
Citations

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277

초록

A new thioamide derivative of 8-hydroxyquinoline-benzothiazole was prepared, and its fluorogenic chemodosimetric behaviors toward transitionmetal ions were investigated. The thioamide derivative showed highly Hg2+-selective fluorescence enhancing properties (167-fold) in 30% aqueous acetonitrile solution. The selective and sensitive signaling behaviors were found to originate from the Hg2+ ion induced transformation of the very weak fluorescent thioamide derivative into a highly fluorescent amide analogue.

키워드

HEAVY-METAL IONS; AQUEOUS-MEDIA; FLUORESCENT CHEMODOSIMETER; MERCURIC ION; HG2+ IONS; RECOGNITION; CHEMOSENSOR; SENSORS; HG(II); DERIVATIVES
제목
Fluorogenic Hg2+-selective chemodosimeter derived from 8-hydroxyquinoline
저자
Song, Ki Cheol; Kim, Jun Soo; Park, Sang Mi; Chung, Kee-Choo; Ahn, Sangdoo; Chang, Suk-Kyu
DOI
10.1021/ol060788b
발행일
2006-08
유형
Article
저널명
Organic Letters
권
8
호
16
페이지
3413 ~ 3416