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Organophotocatalytic Arene Functionalization: C-C and C-B Bond Formation
- Lee, Da Seu;
- Kim, Chung Soo;
- Iqbal, Naila;
- Park, Gyeong Su;
- Son, Kyung-sun;
- ... Cho, Eun Jin
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33초록
Organophotocatalytic C-C and C-B bond formation reactions of aryl halides have been developed in the presence of an organophotosensitizer, 3,7-di([1,1′-biphenyl]-4-yl)-10-(4-(trifluoromethyl)phenyl)-10H-phenoxazine that has highly negative reduction potential at its photoexcited state. The developed reaction conditions are mild and allow the intermolecular C-C bond formation of the generated aryl radical with electron-rich (hetero)arenes and C-B bond formation with bis(pinacolato)diboron. © 2019 American Chemical Society.
키워드
VISIBLE-LIGHT PHOTOREDOX; METAL-FREE; ARYL HALIDES; UNACTIVATED ALKYL; ELECTRON-TRANSFER; DIAZONIUM SALTS; BORYLATION; ARYLATION; PHOTOSENSITIZER
- 제목
- Organophotocatalytic Arene Functionalization: C-C and C-B Bond Formation
- 저자
- Lee, Da Seu; Kim, Chung Soo; Iqbal, Naila; Park, Gyeong Su; Son, Kyung-sun; Cho, Eun Jin
- 발행일
- 2019-12
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 21
- 호
- 24
- 페이지
- 9950 ~ 9953
- 언어
- ENG
- 출판사
- American Chemical Society
- 발행국가
- 미국
- 분량
- 4 페이지
- ISSN
- E 1523-7052
P 1523-7060