Substrate-dependent magneto-thermoelectric properties in FeRh thin films during antiferromagnetic–ferromagnetic phase transition

초록

FeRh undergoes a first-order antiferromagnetic–ferromagnetic (AFM–FM) transition near room temperature that strongly affects electronic transport. Bulk FeRh shows large but localized Thomson responses near the thermally induced transition. Here, we show that this behavior is tunable in thin films. We measure the thermomagnetic responses of near-equimolar FeRh films (20–80 nm) grown on Al2O3, SiO2/Si, and MgO. For films grown on the same substrate, increasing thickness reduces strain and sharpens the AFM–FM transition, yielding a correspondingly sharper Thomson response. Thicker films reach peaks exceeding -250μV K-1 over narrow temperature ranges, whereas thinner films display smaller peaks spanning up to ∼100 K. Changing the substrate alters crystallinity, microstructure, and strain, leading to pronounced differences in the baseline Seebeck coefficient in both phases. These results demonstrate that strain and microstructure enable engineering the magnitude and temperature span of the Thomson effect in FeRh thin films.

키워드