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A covalent triazine framework-based heterogenized Al-Co bimetallic catalyst for the ring-expansion carbonylation of epoxide to beta-lactone
- Rajendiran, Senkuttuvan;
- Natarajan, Prakash;
- Yoon, Sungho
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47초록
Difficulties in product separation and ineffective recycling of the homogenous catalyst deter the mass production of beta-lactones via carbonylation of epoxides. Herein, we address these issues, for the first time, using a recyclable heterogenized catalyst [bpy-CTF-Al(OTf)(2)][Co(CO)(4)] that efficiently converts propylene oxide (PO) to beta-butyrolactone with high selectivity.
키워드
ENANTIOSELECTIVE ALTERNATING COPOLYMERIZATION; ORGANIC FRAMEWORKS; CARBON-MONOXIDE; POLYMERIZATION; CRYSTALLINE; POLYESTERS; CONSTRUCTION; AZIRIDINES; PROPENE; COMPLEX
- 제목
- A covalent triazine framework-based heterogenized Al-Co bimetallic catalyst for the ring-expansion carbonylation of epoxide to beta-lactone
- 저자
- Rajendiran, Senkuttuvan; Natarajan, Prakash; Yoon, Sungho
- 발행일
- 2017
- 유형
- Article
- 저널명
- RSC Advances
- 권
- 7
- 호
- 8
- 페이지
- 4635 ~ 4638
- 언어
- ENG
- 출판사
- ROYAL SOC CHEMISTRY
- 발행국가
- 영국
- 분량
- 4 페이지
- ISSN
- P 2046-2069