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Recyclable Covalent Triazine Framework-based Ru Catalyst for Transfer Hydrogenation of Carbonyl Compounds in Water
- Padmanaban, Sudakar;
- Gunasekar, Gunniya Hariyanandam;
- Lee, Mearae;
- Yoon, Sungho
Citations
WEB OF SCIENCE
30Citations
SCOPUS
32초록
A heterogeneous Ru catalyst, [(bpy-CTF)-RuCl3], which is synthesized by the coordinative immobilization of RuCl3 center dot xH(2)O on a bipyridyl-functionalized covalent triazine framework (bpy-CTF), is an efficient catalyst for the transfer hydrogenation (TH) of various carbonyl compounds into alcohols in water using HCOONa as a benign reducing agent. The as-prepared heterogeneous catalyst exhibits a very high turnover number (similar to 990) and an initial turnover frequency (44.8 h(-1)) as well as excellent recyclability, which makes it a greener catalyst for industrial applications in TH.
키워드
Green chemistry; Heterogeneous catalysis; Covalent triazine framework; Transfer hydrogenation; Ru catalysis; ASYMMETRIC TRANSFER HYDROGENATION; FORMIC-ACID; SUPPORTED PALLADIUM; HIGHLY EFFICIENT; KETONES; NANOPARTICLES; POLYMER; REDUCTION; METHANOL; NANOCATALYSTS
- 제목
- Recyclable Covalent Triazine Framework-based Ru Catalyst for Transfer Hydrogenation of Carbonyl Compounds in Water
- 저자
- Padmanaban, Sudakar; Gunasekar, Gunniya Hariyanandam; Lee, Mearae; Yoon, Sungho
- 발행일
- 2019-05
- 유형
- Article
- 권
- 7
- 호
- 9
- 페이지
- 8893 ~ 8899
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 7 페이지
- ISSN
- P 2168-0485