Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

Sivanesan, Dharmalingam; Yoon, Sungho

doi:10.1016/j.poly.2013.04.011

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Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

Sivanesan, Dharmalingam;
Yoon, Sungho

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22

초록

A Rh(III) complex having a functionalized bpy-OH ligand that is potentially linkable to electrode surfaces was synthesized and fully characterized. The hydrido complex, which could be generated either electrochemically by cathodic reduction of the [eta(5)-Cp*Rh(bpy-OH)ClICI complex at 771 mV (versus Ag/AgCI) or chemically with formate, transformed NAD(+) efficiently into NADH with a TOF = 710 at 60 degrees C. (C) 2013 Elsevier Ltd. All rights reserved.

키워드

NADH regeneration; Indirect electrochemical method; Chemical method; Crystal structure; ASYMMETRIC TRANSFER HYDROGENATION; ELECTROCHEMICAL REGENERATION; BIOORGANOMETALLIC CHEMISTRY; ENZYMATIC REDUCTION; NICOTINAMIDE; COFACTORS; IRIDIUM; WATER; IMMOBILIZATION; BIOCATALYSIS

제목: Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

저자: Sivanesan, Dharmalingam; Yoon, Sungho

DOI: 10.1016/j.poly.2013.04.011

발행일: 2013-07

유형: Article

저널명: Polyhedron

권: 57

페이지: 52 ~ 56

언어: ENG

출판사: PERGAMON-ELSEVIER SCIENCE LTD

발행국가: 영국

분량: 5 페이지

ISSN: E 1873-3719
P 0277-5387