Intrachain fluorescence quenching in a flexible polymer: A theory for frequency-domain fluorometric experiments

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8
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10

초록

We present a theory for analyzing the frequency-domain fluorometric experiments on intrachain fluorescence-quenching reactions occurring in flexible chain polymers. The results are applied to investigate the qualitative dependence of the modulation and the phase angle on the chain length of the polymer, based on the Rouse chain model. (C) 2001 American Institute of Physics.

키워드

Computer Simulation; Conformations; Energy Transfer; Fluorescence; Green's Function; Ground State; Laplace Transforms; Matrix Algebra; Perturbation Techniques; Probability Density Function; Quenching; Flexible Chain Polymers; Fluorophore; Frequency-domain Fluorometric Experiments; Intrachain Fluorescence-quenching Reactions; Polymers; DIFFUSION-CONTROLLED REACTIONS; INTRAMOLECULAR ENERGY-TRANSFER; TO-END DIFFUSION; RESOLUTION; MOLECULES; DYNAMICS; SYSTEMS; CHAINS
제목
Intrachain fluorescence quenching in a flexible polymer: A theory for frequency-domain fluorometric experiments
저자
Sung, Jaeyoung; Lee, Sangyoub
DOI
10.1063/1.1411992
발행일
2001-11
유형
Article
저널명
The Journal of Chemical Physics
권
115
호
19
페이지
9050 ~ 9054