Reaction-based Hg2+ signaling by excimer-monomer switching of a bis-pyrene dithioacetal

  • Cho, Yoonha; 
  • Lee, Seul Ki; 
  • Lee, Jung Woo; 
  • Ahn, Sangdoo; 
  • Chang, Suk-Kyu
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14
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14

초록

A novel reaction-based probe for fluorescence signaling of Hg2+ ions was developed. Selective Hg2+-induced cleavage of a dithioacetal resulting in switching from pyrene excimer to monomer emission was used for the signaling. Changes in excimer and monomer emissions of pyrene were readily employed for ratiometric signaling of Hg2+ ions in aqueous acetonitrile. Selective signaling of Hg2+ ions over other common metal ions was observed with a detection limit of 9.8 x 10(-7) M. (C) 2013 Elsevier Ltd. All rights reserved.

키워드

Hg2+ signaling; Bis-pyrene; Excimer-monomer switching; Dithioacetal; Ratiometry; COLORIMETRIC CHEMODOSIMETER; FLUORESCENT; MERCURY(II); SENSOR; EMISSION; PROBES; SUGAR; IONS
제목
Reaction-based Hg2+ signaling by excimer-monomer switching of a bis-pyrene dithioacetal
저자
Cho, Yoonha; Lee, Seul Ki; Lee, Jung Woo; Ahn, Sangdoo; Chang, Suk-Kyu
DOI
10.1016/j.tetlet.2013.07.109
발행일
2013-09
유형
Article
저널명
Tetrahedron Letters
권
54
호
39
페이지
5341 ~ 5344