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Platinum-Catalyzed Deoxygenation of N-Acyloxyamines
- Ali, Kashif;
- Cho, Eun Jin
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2초록
We report a Pt-catalyzed double deoxygenative transformation of N-acyloxyamines, employing PtCl2 catalyst without external ligand under mild conditions. This method facilitates efficient C-N bond formation and can be used to synthesize a broad spectrum of alkylated secondary and tertiary amines with excellent yields. The adaptability and effectiveness of this approach highlight the potential of platinum catalysis to extend beyond traditional synthetic boundaries.
키워드
platinum; acyloxyamine; deoxygenation; reduction; silane; C-N coupling; REDUCTION; AMIDES; HYDROGENATION; SECONDARY; AMINATION; DOMINO
- 제목
- Platinum-Catalyzed Deoxygenation of N-Acyloxyamines
- 저자
- Ali, Kashif; Cho, Eun Jin
- 발행일
- 2025-02
- 유형
- Article; Early Access
- 저널명
- Synthesis
- 권
- 57
- 호
- 4
- 페이지
- 732 ~ 739
- 언어
- ENG
- 출판사
- GEORG THIEME VERLAG KG
- 발행국가
- 독일
- 분량
- 8 페이지
- ISSN
- E 1437-210X
P 0039-7881