Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst

Moon, Jisu; Moon, Yu Kyung; Park, Do Dam; Choi, Sukyung; You, Youngmin; Cho, Eun Jin

doi:10.1021/acs.joc.9b01624

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Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst

Moon, Jisu;
Moon, Yu Kyung;
Park, Do Dam;
Choi, Sukyung;
You, Youngmin;
... Cho, Eun Jin

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WEB OF SCIENCE

37

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SCOPUS

42

초록

Tri(9-anthryl)borane was successfully applied as an organophotocatalyst for the visible-light-induced trifluoromethylation of unactivated alkenes with CF3I. The mild reaction conditions tolerated a variety of functional groups, and the reaction could be extended to perfluoroalkylations with C3F7I and C4F9I. Mechanistic studies revealed that the photoredox catalysis involves an oxidative quenching pathway.

키워드

CATALYZED TRIFLUOROMETHYLATION; IRRADIATION; DERIVATIVES; COMPLEXES

제목: Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst

저자: Moon, Jisu; Moon, Yu Kyung; Park, Do Dam; Choi, Sukyung; You, Youngmin; Cho, Eun Jin

DOI: 10.1021/acs.joc.9b01624

발행일: 2019-10

유형: Article

저널명: The Journal of Organic Chemistry

권: 84

호: 20

페이지: 12925 ~ 12932