Selective difluoroalkylation of alkenes by using visible light photoredox catalysis

  • Yu, Chunghyeon; 
  • Iqbal, Naeem; 
  • Park, Sehyun; 
  • Cho, Eun Jin
Citations

WEB OF SCIENCE

236
Citations

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237

초록

A visible light-induced process for selective difluoroalkylation of unactivated alkenes has been developed. The choice of base is crucial for governing the chemoselectivity of the process to produce difluoroalkylated alkanes and alkenes.

키워드

ETHYL BROMODIFLUOROACETATE; RADICAL-ADDITION; TRIFLUOROMETHYLATION; DIFLUOROMETHYLATION; HETEROARENES; DERIVATIVES; FLUORINE; PERFLUOROALKYLATION; IODODIFLUOROACETATE; FUNCTIONALIZATION
제목
Selective difluoroalkylation of alkenes by using visible light photoredox catalysis
저자
Yu, Chunghyeon; Iqbal, Naeem; Park, Sehyun; Cho, Eun Jin
DOI
10.1039/c4cc05467a
발행일
2014-11
유형
Article
저널명
Chemical Communications
권
50
호
85
페이지
12884 ~ 12887