Chemical transformation of solution-processed Ag nanocrystal thin films into electrically conductive and catalytically active Pt-based nanostructures

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초록

Efficient methods for the controlled syntheses of metal nanocrystals are important for emerging electronics and catalysis applications. In this report, we present a solution-based method for the fabrication of Pt-coated Ag nanocrystal (NC) thin films through the use of ligand-exchange and electroless deposition. We successfully prepared uniform or bumpy Ag@Pt core/shell structures, as well as Ag–Pt alloy structures, through control of the reducing agents. We first report the Ag–Pt alloy structures can be synthesized by low-temperature and solution-based process of post treatment that exhibited high catalytic activity toward the hydrogen evolution reaction. © 2019 The Korean Society of Industrial and Engineering Chemistry

키워드

Electroless deposition; Galvanic displacement; Hydrogen evolution reaction; Pt–Ag alloy structure; Silver nanocrystal; Catalyst activity; Conductive films; Deposition; Electroless plating; Nanocrystals; Platinum alloys; Reducing agents; Silver alloys; Temperature; Thin films; Ag-alloy; Chemical transformations; Controlled synthesis; Electrically conductive; Galvanic displacement; Hydrogen evolution reactions; Silver nanocrystals; Solution-based process; Nanocrystalline alloys
제목
Chemical transformation of solution-processed Ag nanocrystal thin films into electrically conductive and catalytically active Pt-based nanostructures
저자
Seong, Mingi; Kim, Hoyoung; Woo, Ho Young; Hossain, Md Ashraf; Ahn, Jun Hyuk; Kim, Soo-Kil; Paik, Taejong; Oh, Soong Ju
DOI
10.1016/j.jiec.2019.04.004
발행일
2019-08
유형
Article
저널명
Journal of Industrial and Engineering Chemistry
권
76
페이지
388 ~ 395