Visible-light-induced installation of oxyfluoroalkyl groups

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13

초록

(Hetero)aryloxytetrafluoroethylation of heteroaromatics and alkenes has been achieved by visible-light photocatalysis utilizing readily synthesized oxyfluoroalkyl reagents. The mild reaction conditions and the high diversity on both substrates and oxyfluoroalkyl reagents make this a useful method for late-stage modifications in the development of various functional molecules.

키워드

MEDIATED OXIDATIVE TRIFLUOROMETHYLATION; ALPHA-FLUORINATED ETHERS; PHOTOREDOX CATALYSIS; SUBSTITUENT CONSTANTS; MEDICINAL CHEMISTRY; CONTINUOUS-FLOW; HETEROARENES; ARENES; FLUOROALKYLATION; HETEROCYCLES
제목
Visible-light-induced installation of oxyfluoroalkyl groups
저자
Park, Gwi-Rim; Moon, Jisu; Cho, Eun Jin
DOI
10.1039/c7cc08067k
발행일
2017-12
유형
Article
저널명
Chemical Communications
권
53
호
95
페이지
12786 ~ 12789