The first hydride-Meisenheimer adduct of electron-deficient 3-nitronaphthalimide: application to colorimetric borohydride determination

  • Choi, Myung Gil; 
  • Kim, Na Yeong; 
  • Lee, Yu Jeong; 
  • Ahn, Sangdoo; 
  • Chang, Suk-Kyu
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초록

The first hydride-Meisenheimer adduct of 3-nitronaphthalimide was used for the colorimetric borohydride assay. To explain the regioselectivity of the adduct, the reaction enthalpies of the two most plausible Meisenheimer adducts were obtained via computational calculation. Using the adduct formation, the assay of borohydride reagents was successfully conducted.

키워드

SODIUM-BOROHYDRIDE; SPECTROPHOTOMETRIC DETERMINATION; HYDROLYSIS
제목
The first hydride-Meisenheimer adduct of electron-deficient 3-nitronaphthalimide: application to colorimetric borohydride determination
저자
Choi, Myung Gil; Kim, Na Yeong; Lee, Yu Jeong; Ahn, Sangdoo; Chang, Suk-Kyu
DOI
10.1039/c9cc05597e
발행일
2019-09
유형
Article
저널명
Chemical Communications
권
55
호
76
페이지
11398 ~ 11401