Facile fabrication of nanostructured NiMo cathode for high-performance proton exchange membrane water electrolyzer

  • Kim, J.; 
  • Kim, J.; 
  • Kim, H.; 
  • Kim, J.; 
  • Ahn, S.H.
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초록

Clean hydrogen production via water electrolyzer connected with renewable energies is an essential technology for a sustainable energy in future. To realize the system, development of high-performance electrode remains a challenge. In this study, simple cathodic electrodepositions allow for the facile fabrication of a nanostructured non-noble metal cathode. Under optimized deposition condition, the NiMo catalyst supported by Cu foam exhibits overpotential of 68.7 mV at −10 mA/cm2 for hydrogen evolution reaction in acidic medium. The proton exchange membrane water electrolyzer employing the cathode demonstrates a remarkable current density of ˜2.0 A/cm2 at 2.0 V, which is the highest performance among state-of-the-art non-noble cathodes reported to date. The results presented herein indicate a promising cost-effective cathode for practical applications. © 2019 The Korean Society of Industrial and Engineering Chemistry

키워드

Electrocatalyst; Electrodeposition; Gas diffusion electrode; Hydrogen evolution reaction; Proton exchange membrane water electrolyzer; Water electrolysis; HYDROGEN-EVOLUTION REACTION; MOLYBDENUM CARBIDE; NICKEL PHOSPHIDE; CATALYST; ELECTROCATALYST; EFFICIENT; NANOWIRE; DEGRADATION; ELECTRODES; SULFIDE
제목
Facile fabrication of nanostructured NiMo cathode for high-performance proton exchange membrane water electrolyzer
저자
Kim, J.; Kim, J.; Kim, H.; Kim, J.; Ahn, S.H.
DOI
10.1016/j.jiec.2019.06.049
발행일
2019-11
유형
Article
저널명
Journal of Industrial and Engineering Chemistry
권
79
페이지
255 ~ 260