실리콘-알루미늄 몰 비의 변화에 따른 메타카올린 지오폴리머의 나노인덴테이션 결과 분석을 위한 가우시안 믹스쳐 모델의 활용

초록

This study proposes the deconvolution method for the nanoindentation test results of geopolymer employing the Gaussian mixture model. Geopolymer has been studied extensively as an alternative construction material because it emits relatively lower CO2 compared to ordinary Portland cement. Geopolymer is made of aluminosilicate and alkaline solution, and the Si/Al molar ratio affects its mechanical properties. Previous studies revealed that the Si/Al molar ratio of 1.8~2.0 results in the highest compressive strength, and the Si/Al molar ratio over 1.8 degrades the compressive strength of geopolymer severely; however the reason for the compressive strength degradation is still unclear. To understand the effect of the Si/Al molar ratio on the geopolymer structure, this study exploits the nanoindentation. The phase deconvolution of the indent modulus data is successful using the Gaussian mixture model, and it is observed that the Si/Al molar ratio alters the homogeneity of the geopolymer. Geopolymer becomes more homogeneous up to an Si/Al molar ratio of 1.8 at which geopolymer exhibits the highest compressive strength. The examination of this study is assumed to be adopted as evidence of strength degradation by the Si/Al ratio higher than the optimum value.

키워드